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01 July 2013

Interstellar gas allows chemical reactions caused by quantum tunneling

The gas cloud around these stars could be undergoing chemical reactions that we had previously thought were impossible. (NASA)
 
In recent years, astronomers have detected some simple organic chemicals in the disks of material surrounding some stars. In our own Solar System, these seem to have undergone reactions that converted them into more complex molecules - some of them crucial for life - that have been found on meteorites.
 
So, understanding the reactions that can take place in space can help provide an indication of the sorts of chemistry available to start life both here and around other stars.
 
Based on a publication in Nature Chemistry, it seems that the chemistry that can take place in the cold clouds of gas of space is much more complex than we had predicted. Reactions that would be impossible under normal circumstances - simply because there's not enough energy to push them forward - can take place in cold gasses due to quantum mechanical effects. That's because one of the reactants (a hydrogen nucleus) can undergo quantum tunneling between two reactants.
 
The fact that quantum tunneling allows reactions that would never take place in their own right is pretty impressive. But the results are also important because they give us a clearer picture of what's likely to be going on in the neighborhood of distant stars. Because of their distance, it's hard to detect anything other than raw materials around them. To infer the actual chemistry of the gas clouds, we have to look at the raw materials and the conditions, then figure out what reactions are likely to take place.
 
By confirming that otherwise-impossible reactions can take place in these gas clouds, the authors have greatly expanded the range of chemistry we can expect to be taking place. And that can tell us something about the chemicals that are likely to be present in any planets formed under similar conditions.